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Meso-N-methylation of a porphyrinoid complex: Activating the H-atom transfer capability of an inert Re(V)(O) corrolazine()
The selective alkylation of a single meso-N atom of a corrolazine macrocycle is reported. Alkylation has a dramatic impact on the physicochemical properties of Re(V)(O)(TBP(8)Cz). New electron-transfer and hydrogen-atom-transfer reactivity is also seen for this complex, including one-electron reduct...
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| Udgivet i: | Chem Commun (Camb) |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5351293/ https://ncbi.nlm.nih.gov/pubmed/28119963 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc09341h |
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