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Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity()
The synthesis of the first example of a third-row metallocorrolazine characterized by single crystal X-ray diffraction is reported. This Re(V)(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-cation-radical compl...
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| izdano v: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4679572/ https://ncbi.nlm.nih.gov/pubmed/26507380 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc07956j |
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