Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction

Isomorphous crystals of Mn(V)(O) and Cr(V)(O) corrolazines were characterized by single crystal X-ray diffraction. Reactivity studies with H-atom donors and separated PCET reagents show a dramatic difference in H-atom abstracting abilities for these two complexes. The implied large difference in dri...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Baglia, Regina A., Prokop-Prigge, Katharine A., Neu, Heather M., Siegler, Maxime A., Goldberg, David P.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2015
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4880368/
https://ncbi.nlm.nih.gov/pubmed/26295412
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05142
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