Laddar...
Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-radical-cation)(Lewis acid) Versus Mn(V)(O) Porphyrinoid Complexes
The oxygen atom transfer (OAT) reactivity of two valence tautomers of a Mn(V)(O) porphyrinoid complex was compared. The OAT kinetics of Mn(V)(O)(TBP(8)Cz) (TBP(8)Cz = octakis(p-tert-butylphenyl)corrolazinato(3−)) reacting with a series of triarylphosphine (PAr(3)) substrates were monitored by stoppe...
Sparad:
| I publikationen: | J Am Chem Soc |
|---|---|
| Huvudupphovsmän: | , , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2015
|
| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4888055/ https://ncbi.nlm.nih.gov/pubmed/25964988 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00875 |
| Taggar: |
Lägg till en tagg
Inga taggar, Lägg till första taggen!
|