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Intramolecular vinylation of aryl rings by vinyl cations

A Lewis acid mediated intramolecular electrophilic vinylation of aryl rings by vinyl cations is reported. This reaction takes advantage of β-hydroxy-α-diazo ketones as vinyl cation precursors and provides good yields of tricyclic 1-indenones that contain a 7-membered ring. Extending the alkane chain...

詳細記述

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書誌詳細
出版年:Org Lett
主要な著者: Fang, Jian, Brewer, Matthias
フォーマット: Artigo
言語:Inglês
出版事項: 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7045802/
https://ncbi.nlm.nih.gov/pubmed/30426753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b03054
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