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Intramolecular vinylation of aryl rings by vinyl cations
A Lewis acid mediated intramolecular electrophilic vinylation of aryl rings by vinyl cations is reported. This reaction takes advantage of β-hydroxy-α-diazo ketones as vinyl cation precursors and provides good yields of tricyclic 1-indenones that contain a 7-membered ring. Extending the alkane chain...
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| Publicado en: | Org Lett |
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| Autores principales: | , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7045802/ https://ncbi.nlm.nih.gov/pubmed/30426753 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b03054 |
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