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Intramolecular vinylation of aryl rings by vinyl cations
A Lewis acid mediated intramolecular electrophilic vinylation of aryl rings by vinyl cations is reported. This reaction takes advantage of β-hydroxy-α-diazo ketones as vinyl cation precursors and provides good yields of tricyclic 1-indenones that contain a 7-membered ring. Extending the alkane chain...
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| Gepubliceerd in: | Org Lett |
|---|---|
| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2018
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7045802/ https://ncbi.nlm.nih.gov/pubmed/30426753 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b03054 |
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