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Substituted α-alkylidene cyclopentenones via the intramolecular reaction of vinyl cations with alkenes

Substituted α-alkylidene cyclopentenones are formed in up to 93% yield by the intramolecular capture of vinyl cations with pendent alkenes. An increased level of substitution at the β-position of the β-hydroxy-α-diazoketone starting material changed the course of the reaction to instead give a lacto...

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Enregistré dans:
Détails bibliographiques
Publié dans:Org Lett
Auteurs principaux: Hensinger, Magenta J., Dodge, Nicholas J., Brewer, Matthias
Format: Artigo
Langue:Inglês
Publié: 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7045725/
https://ncbi.nlm.nih.gov/pubmed/31873030
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b04255
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