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Remote C–H insertion of vinyl cations leading to cyclopentenones
We report a Lewis acid catalyzed reaction sequence involving a 1,2-shift and subsequent C–H insertion that gives monocyclic and fused bicyclic cyclopentenone products. This reaction sequence, which is initiated by treating β-hydroxy-α-diazo ketones with a Lewis acid, proceeds through vinyl cation in...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2017
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5643953/ https://ncbi.nlm.nih.gov/pubmed/29147505 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02768k |
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