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Teaching an old carbocation new tricks: Intermolecular C–H insertion reactions of vinyl cations

Vinyl carbocations have been the subject of extensive experimental and theoretical studies over the past five decades. Despite this long history in chemistry, the utility of vinyl cations in chemical synthesis has been limited, with most reactivity studies focusing on solvolysis reactions or intramo...

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Dettagli Bibliografici
Pubblicato in:Science
Autori principali: Popov, Stasik, Shao, Brian, Bagdasarian, Alex L., Benton, Tyler R., Zou, Luyi, Yang, Zhongyue, Houk, K. N., Nelson, Hosea M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6688626/
https://ncbi.nlm.nih.gov/pubmed/30049877
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aat5440
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