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Vinyl Carbocations Generated under Basic Conditions and Their Intramolecular C–H Insertion Reactions
Here we report the surprising discovery that high-energy vinyl carbocations can be generated under strongly basic conditions, and that they engage in intramolecular sp(3) C–H insertion reactions through the catalysis of weakly coordinating anion salts. This approach relies on the unconventional comb...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6608570/ https://ncbi.nlm.nih.gov/pubmed/31082208 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02110 |
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