Vinyl Carbocations Generated under Basic Conditions and Their Intramolecular C–H Insertion Reactions

Here we report the surprising discovery that high-energy vinyl carbocations can be generated under strongly basic conditions, and that they engage in intramolecular sp(3) C–H insertion reactions through the catalysis of weakly coordinating anion salts. This approach relies on the unconventional comb...

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Publicat a:J Am Chem Soc
Autors principals: Wigman, Benjamin, Popov, Stasik, Bagdasarian, Alex L., Shao, Brian, Benton, Tyler R., Williams, Chloé G., Fisher, Steven P., Lavallo, Vincent, Houk, K. N., Nelson, Hosea M.
Format: Artigo
Idioma:Inglês
Publicat: 2019
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6608570/
https://ncbi.nlm.nih.gov/pubmed/31082208
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02110
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