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Decreasing Distortion Energies without Strain: Diazo-Selective 1,3-Dipolar Cycloadditions
The diazo group has attributes that complement those of the azido group for applications in chemical biology. Here, we use computational analyses to provide insights into the chemoselectivity of the diazo group in 1,3-dipolar cycloadditions. Dipole distortion energies are responsible for ~80% of the...
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| 出版年: | J Org Chem |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5141247/ https://ncbi.nlm.nih.gov/pubmed/27332711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b00948 |
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