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1,3-Dipolar Cycloaddition with Diazo Groups: Noncovalent Interactions Overwhelm Strain
Like azides, diazoacetamides undergo 1,3-dipolar cycloadditions with oxanorbornadienes (OND) in a reaction that is accelerated by the relief of strain in the transition state. The cycloaddition of a diazoacetamide with unstrained ethyl 4,4,4-trifluoro-2-butynoate is, however, 35-fold faster than wit...
Gardado en:
| Publicado en: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5148626/ https://ncbi.nlm.nih.gov/pubmed/27599159 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01938 |
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