Llwytho...

Rapid cycloaddition of a diazo group with an unstrained dipolarophile

The cycloaddition of a diazoacetamide with ethyl 4,4,4-trifluorocrotonate proceeds with k = 0.1 M(−1)s(−1). This second-order rate constant rivals those of optimized strain-promoted azide– alkyne cycloadditions, even though the reaction does not release strain. The regioselectivity and a computation...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Tetrahedron Lett
Prif Awduron: Aronoff, Matthew R., Gold, Brian, Raines, Ronald T.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2016
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5125787/
https://ncbi.nlm.nih.gov/pubmed/27909348
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.04.020
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