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Rapid cycloaddition of a diazo group with an unstrained dipolarophile
The cycloaddition of a diazoacetamide with ethyl 4,4,4-trifluorocrotonate proceeds with k = 0.1 M(−1)s(−1). This second-order rate constant rivals those of optimized strain-promoted azide– alkyne cycloadditions, even though the reaction does not release strain. The regioselectivity and a computation...
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| Publicado no: | Tetrahedron Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5125787/ https://ncbi.nlm.nih.gov/pubmed/27909348 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.04.020 |
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