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Decreasing Distortion Energies without Strain: Diazo-Selective 1,3-Dipolar Cycloadditions
The diazo group has attributes that complement those of the azido group for applications in chemical biology. Here, we use computational analyses to provide insights into the chemoselectivity of the diazo group in 1,3-dipolar cycloadditions. Dipole distortion energies are responsible for ~80% of the...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5141247/ https://ncbi.nlm.nih.gov/pubmed/27332711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b00948 |
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