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1,3-Dipolar Cycloadditions of Diazo Compounds in the Presence of Azides
The diazo group has untapped utility in chemical biology. The tolerance of stabilized diazo groups to cellular metabolism is comparable to that of azido groups. Yet, chemoselectivity has been elusive, as both groups undergo 1,3-dipolar cycloadditions with strained alkynes. Removing strain and tuning...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5141246/ https://ncbi.nlm.nih.gov/pubmed/26981746 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00278 |
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