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Enantioselective Synthesis of α-Oxy Amides via Umpolung Amide Synthesis
α-Oxy amides are prepared through enantioselective synthesis using a sequence beginning with a Henry addition of bromonitromethane to aldehydes, and finishing with Umpolung Amide Synthesis (UmAS). Key to high enantioselection is the finding that ortho-iodo benzoic acid salts of the chiral copper(II)...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2012
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3477818/ https://ncbi.nlm.nih.gov/pubmed/22967461 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja306225u |
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