Umpolung Amide Synthesis Using Substoichiometric N-Iodosuccinimide (NIS) and Oxygen as a Terminal Oxidant

[Image: see text] Umpolung Amide Synthesis (UmAS) provides direct access to amides from an α-bromo nitroalkane and an amine. Based on its mechanistic bifurcation after convergent C–N bond formation, depending on the absence or presence of oxygen, UmAS using substoichiometric N-iodosuccinimide (NIS)...

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Egile Nagusiak: Schwieter, Kenneth E., Shen, Bo, Shackleford, Jessica P., Leighty, Matthew W., Johnston, Jeffrey N.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Chemical Society 2014
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4168777/
https://ncbi.nlm.nih.gov/pubmed/25198239
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol502089v
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