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Discovery of competing anaerobic and aerobic pathways in umpolung amide synthesis allows for site-selective amide (18)O-labeling
The mechanism of umpolung amide synthesis was probed by interrogating potential sources for the oxygen of the product amide carbonyl that emanates from the α-bromo nitroalkane substrate. Using a series of (18)O-labeled substrates and reagents, evidence is gathered to advance two pathways from the pu...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
National Academy of Sciences
2012
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3252937/ https://ncbi.nlm.nih.gov/pubmed/22184227 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1113553108 |
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