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Kinetic isotope effects for RNA cleavage by 2'-O- transphosphorylation: Nucleophilic activation by specific base
To better understand the interactions between catalysts and transition states during RNA strand cleavage, primary (18)O kinetic isotope effects and solvent D(2)O isotope effects were measured to probe the mechanism of base-catalyzed 2'-O-transphosphorylation of the RNA dinucleotide 5'-UpG-...
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| Główni autorzy: | , , , , , |
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| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
2010
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2946848/ https://ncbi.nlm.nih.gov/pubmed/20669950 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103550e |
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