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Functional Characterization of tlmK Unveiling Unstable Carbinolamide Intermediates in the Tallysomycin Biosynthetic Pathway

Tallysomycins (TLMs) belong to the bleomycin family of anticancer antibiotics. TLMs differ from bleomycins primarily by the presence of a 4-amino-4,6-dideoxy-l-talose sugar attached to C-41 as part of a glycosylcarbinolamide. We previously proposed, on the basis of bioinformatics analysis of the tlm...

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Bibliographische Detailangaben
Hauptverfasser: Wang, Liyan, Tao, Meifeng, Wendt-Pienkoski, Evelyn, Galm, Ute, Coughlin, Jane M., Shen, Ben
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Society for Biochemistry and Molecular Biology 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2659183/
https://ncbi.nlm.nih.gov/pubmed/19189972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M900640200
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