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Functional Characterization of tlmK Unveiling Unstable Carbinolamide Intermediates in the Tallysomycin Biosynthetic Pathway

Tallysomycins (TLMs) belong to the bleomycin family of anticancer antibiotics. TLMs differ from bleomycins primarily by the presence of a 4-amino-4,6-dideoxy-l-talose sugar attached to C-41 as part of a glycosylcarbinolamide. We previously proposed, on the basis of bioinformatics analysis of the tlm...

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Detalhes bibliográficos
Main Authors: Wang, Liyan, Tao, Meifeng, Wendt-Pienkoski, Evelyn, Galm, Ute, Coughlin, Jane M., Shen, Ben
Formato: Artigo
Idioma:Inglês
Publicado em: American Society for Biochemistry and Molecular Biology 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2659183/
https://ncbi.nlm.nih.gov/pubmed/19189972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M900640200
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