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Stereospecific Formation of Interstrand Carbinolamine DNA Crosslinks by Crotonaldehyde- and Acetaldehyde-Derived α-CH(3)-γ-OH-1,N(2)-Propano-2’-deoxyguanosine Adducts in the 5′-CpG-3′ Sequence
The crotonaldehyde- and acetaldehyde-derived R- and S-α-CH(3)-γ-OH-1,N(2)-propanodeoxyguanosine adducts were monitored in single-stranded and duplex oligodeoxynucleotides using NMR spectroscopy. In both instances the cis and trans diastereomers of the α-CH(3) and γ-OH groups underwent slow exchange,...
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| Main Authors: | , , , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2631444/ https://ncbi.nlm.nih.gov/pubmed/16485895 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx050239z |
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