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Stereospecific Formation of the (R)-γ-Hydroxytrimethylene Interstrand N(2)-dG:N(2)-dG Cross-Link Arising from the γ-OH-1,N(2)-Propano-2'-deoxyguanosine Adduct in the 5′-CpG-3′ DNA Sequence

Acrolein reacts with dG to form hydroxylated 1,N(2)-propanodeoxyguanosine (OH-PdG) adducts. Most abundant are the epimeric 3-(2-deoxy-β-D-erythro-pentofuranosyl)-5,6,7,8-tetrahydro-8-hydroxypyrimido[1,2a] purin-10(3H)-ones, commonly referred to as the γ-OH-PdG adduct. When placed complementary to de...

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Detalhes bibliográficos
Main Authors: Huang, Hai, Kim, Hye-Young, Kozekov, Ivan D., Cho, Young-Jin, Wang, Hao, Kozekova, Albena, Harris, Thomas H., Rizzo, Carmelo J., Stone, Michael P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2753404/
https://ncbi.nlm.nih.gov/pubmed/19530727
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja809543j
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