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Direct Synthesis of Enamides via Electrophilic Activation of Amides

[Image: see text] A novel, one-step N-dehydrogenation of amides to enamides is reported. This reaction employs the unlikely combination of LiHMDS and triflic anhydride, which serves as both the electrophilic activator and the oxidant, and is characterized by its simple setup and broad substrate scop...

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Publicat a:J Am Chem Soc
Autors principals: Spieß, Philipp, Berger, Martin, Kaiser, Daniel, Maulide, Nuno
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2021
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8299460/
https://ncbi.nlm.nih.gov/pubmed/34232035
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c04363
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