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Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides
[Image: see text] A new approach for the synthesis of 1,4-dicarbonyl compounds is reported. Chemoselective activation of amide carbonyl functionality and subsequent umpolung viaN-oxide addition generates an electrophilic enolonium species that can be coupled with a wide range of nucleophilic enolate...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American Chemical
Society
2017
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5691317/ https://ncbi.nlm.nih.gov/pubmed/29099184 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08813 |
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