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Regioselective synthesis of pyridines by redox alkylation of pyridine N-oxides with malonates
ABSTRACT: A regioselective synthesis of pyridines by the addition of malonate anions to pyridine N-oxide derivatives, which have been activated by trifluoromethanesulfonic anhydride, is reported. The reaction selectively affords either 2- or 4-substituted pyridines in good yields. GRAPHICAL ABSTRACT...
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| Publicado no: | Monatsh Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Springer Vienna
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5906502/ https://ncbi.nlm.nih.gov/pubmed/29681655 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-017-2081-y |
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