Yüklüyor......

Chemoselective Alpha‐Deuteration of Amides via Retro‐ene Reaction

A synthetically convenient approach for the direct α‐deuteration of amides is reported. This mechanistically unusual process relies on a retro‐ene‐type process, triggered by the addition of deuterated dimethyl sulfoxide to a keteniminium intermediate, generated through electrophilic amide activation...

Ful tanımlama

Kaydedildi:
Detaylı Bibliyografya
Yayımlandı:Chemistry
Asıl Yazarlar: Porte, Vincent, Di Mauro, Giovanni, Schupp, Manuel, Kaiser, Daniel, Maulide, Nuno
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2020
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756638/
https://ncbi.nlm.nih.gov/pubmed/33035360
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004103
Etiketler: Etiketle
Etiket eklenmemiş, İlk siz ekleyin!