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Chemoselective Alpha‐Deuteration of Amides via Retro‐ene Reaction
A synthetically convenient approach for the direct α‐deuteration of amides is reported. This mechanistically unusual process relies on a retro‐ene‐type process, triggered by the addition of deuterated dimethyl sulfoxide to a keteniminium intermediate, generated through electrophilic amide activation...
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| Izdano u: | Chemistry |
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| Glavni autori: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2020
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756638/ https://ncbi.nlm.nih.gov/pubmed/33035360 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004103 |
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