The duality of electron localization and covalency in lanthanide and actinide metallocenes

Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce(C(8)H(8))(2), have provided evidence for non-negligible 4f-electron density on Ce and implied that charge transfer from the ligands occurs as a result of covalent bonding. Strong correlations of the localized 4f-electrons to t...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Smiles, Danil E., Batista, Enrique R., Booth, Corwin H., Clark, David L., Keith, Jason M., Kozimor, Stosh A., Martin, Richard L., Minasian, Stefan G., Shuh, David K., Stieber, S. Chantal E., Tyliszczak, Tolek
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8157540/
https://ncbi.nlm.nih.gov/pubmed/34084340
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06114b
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