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The duality of electron localization and covalency in lanthanide and actinide metallocenes

Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce(C(8)H(8))(2), have provided evidence for non-negligible 4f-electron density on Ce and implied that charge transfer from the ligands occurs as a result of covalent bonding. Strong correlations of the localized 4f-electrons to t...

詳細記述

保存先:
書誌詳細
出版年:Chem Sci
主要な著者: Smiles, Danil E., Batista, Enrique R., Booth, Corwin H., Clark, David L., Keith, Jason M., Kozimor, Stosh A., Martin, Richard L., Minasian, Stefan G., Shuh, David K., Stieber, S. Chantal E., Tyliszczak, Tolek
フォーマット: Artigo
言語:Inglês
出版事項: The Royal Society of Chemistry 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC8157540/
https://ncbi.nlm.nih.gov/pubmed/34084340
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06114b
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