Electron localization in a mixed-valence diniobium benzene complex

Reaction of the neutral diniobium benzene complex {[Nb(BDI)N( t )Bu](2)(μ-C(6)H(6))} (BDI = N,N′-diisopropylbenzene-β-diketiminate) with Ag[B(C(6)F(5))(4)] results in a single electron oxidation to produce a cationic diniobium arene complex, {[Nb(BDI)N( t )Bu](2)(μ-C(6)H(6))}{B(C(6)F(5))(4)}. Invest...

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Udgivet i:Chem Sci
Main Authors: Gianetti, Thomas L., Nocton, Grégory, Minasian, Stefan G., Kaltsoyannis, Nikolas, Kilcoyne, A. L. David, Kozimor, Stosh A., Shuh, David K., Tyliszczak, Tolek, Bergman, Robert G., Arnold, John
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2015
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811154/
https://ncbi.nlm.nih.gov/pubmed/29560186
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02705a
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