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High-Pressure Spectral Studies of Mixed Valence Compounds of Antimony
In Cs(2)SbCl(6) and related compounds antimony appears as Sb(III) and Sb(V) in alternate halide octahedra. The optical spectrum contains “mixed valence” peaks assigned to Sb(III) → Sb(V) transfer near 18 and 27 kK (cm(-1)). In addition there is a peak near 31 kK assigned to an internal transition on...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1973
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC427170/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592115/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.70.11.3065 |
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