High-Pressure Spectral Studies of Mixed Valence Compounds of Antimony

In Cs(2)SbCl(6) and related compounds antimony appears as Sb(III) and Sb(V) in alternate halide octahedra. The optical spectrum contains “mixed valence” peaks assigned to Sb(III) → Sb(V) transfer near 18 and 27 kK (cm(-1)). In addition there is a peak near 31 kK assigned to an internal transition on...

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發表在:	Proc Natl Acad Sci U S A
Principais autores:	Chiu, V. C. K., Drickamer, H. G.
格式:	Artigo
語言:	Inglês
出版:	National Academy of Sciences 1973
主題:	Physical Sciences: Chemistry
在線閱讀:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC427170/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592115/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.70.11.3065
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