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The duality of electron localization and covalency in lanthanide and actinide metallocenes
Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce(C(8)H(8))(2), have provided evidence for non-negligible 4f-electron density on Ce and implied that charge transfer from the ligands occurs as a result of covalent bonding. Strong correlations of the localized 4f-electrons to t...
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| Опубликовано в: : | Chem Sci |
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| Главные авторы: | , , , , , , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
The Royal Society of Chemistry
2020
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8157540/ https://ncbi.nlm.nih.gov/pubmed/34084340 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06114b |
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