The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

Across the periodic table the trans-influence operates, whereby tightly bonded ligands selectively lengthen mutually trans metal–ligand bonds. Conversely, in high oxidation state actinide complexes the inverse-trans-influence operates, where normally cis strongly donating ligands instead reside tran...

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Publié dans:Nat Commun
Auteurs principaux: Gregson, Matthew, Lu, Erli, Mills, David P., Tuna, Floriana, McInnes, Eric J. L., Hennig, Christoph, Scheinost, Andreas C., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Kerridge, Andrew, Liddle, Stephen T.
Format: Artigo
Langue:Inglês
Publié: Nature Publishing Group 2017
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5296655/
https://ncbi.nlm.nih.gov/pubmed/28155857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms14137
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