[U(III){N(SiMe(2)tBu)(2)}(3)]: A Structurally Authenticated Trigonal Planar Actinide Complex

We report the synthesis and characterization of the uranium(III) triamide complex [U(III)(N**)(3)] [1, N**=N(SiMe(2)tBu)(2)(−)]. Surprisingly, complex 1 exhibits a trigonal planar geometry in the solid state, which is unprecedented for three-coordinate actinide complexes that have exclusively adopte...

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Bibliographic Details
Published in:Chemistry
Main Authors: Goodwin, Conrad AP, Tuna, Floriana, McInnes, Eric JL, Liddle, Stephen T, McMaster, Jonathan, Vitorica-Yrezabal, Inigo J, Mills, David P
Format: Artigo
Language:Inglês
Published: WILEY-VCH Verlag 2014
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4260841/
https://ncbi.nlm.nih.gov/pubmed/25241882
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201404864
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