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[U(III){N(SiMe(2)tBu)(2)}(3)]: A Structurally Authenticated Trigonal Planar Actinide Complex
We report the synthesis and characterization of the uranium(III) triamide complex [U(III)(N**)(3)] [1, N**=N(SiMe(2)tBu)(2)(−)]. Surprisingly, complex 1 exhibits a trigonal planar geometry in the solid state, which is unprecedented for three-coordinate actinide complexes that have exclusively adopte...
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| Pubblicato in: | Chemistry |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
WILEY-VCH Verlag
2014
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4260841/ https://ncbi.nlm.nih.gov/pubmed/25241882 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201404864 |
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