Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds

We report comparable levels of covalency in cerium– and uranium–carbon multiple bonds in the iso-structural carbene complexes [M(BIPM(TMS))(ODipp)(2)] [M = Ce (1), U (2), Th (3); BIPM(TMS) = C(PPh(2)NSiMe(3))(2); Dipp = C(6)H(3)-2,6-(i)Pr(2)] whereas for M = Th the M[double bond, length as m-dash]C...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Gregson, Matthew, Lu, Erli, Tuna, Floriana, McInnes, Eric J. L., Hennig, Christoph, Scheinost, Andreas C., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Kerridge, Andrew, Liddle, Stephen T.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6006499/
https://ncbi.nlm.nih.gov/pubmed/29997821
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00278a
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