Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide**

Two-electron reductive carbonylation of the uranium(VI) nitride [U(Tren(TIPS))(N)] (2, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)) with CO gave the uranium(IV) cyanate [U(Tren(TIPS))(NCO)] (3). KC(8) reduction of 3 resulted in cyanate dissociation to give [U(Tren(TIPS))] (4) and KNCO, or cyanate retention...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Cleaves, Peter A, King, David M, Kefalidis, Christos E, Maron, Laurent, Tuna, Floriana, McInnes, Eric J L, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2014
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4497608/
https://ncbi.nlm.nih.gov/pubmed/25079093
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201406203
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