Evidence for single metal two electron oxidative addition and reductive elimination at uranium

Reversible single-metal two-electron oxidative addition and reductive elimination are common fundamental reactions for transition metals that underpin major catalytic transformations. However, these reactions have never been observed together in the f-block because these metals exhibit irreversible...

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Publicat a:Nat Commun
Autors principals: Gardner, Benedict M., Kefalidis, Christos E., Lu, Erli, Patel, Dipti, McInnes, Eric J. L., Tuna, Floriana, Wooles, Ashley J., Maron, Laurent, Liddle, Stephen T.
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2017
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5711956/
https://ncbi.nlm.nih.gov/pubmed/29196691
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-017-01363-0
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