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Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine–Titanium Complex

Catalytic reduction of N(2) to NH(3) by a Ti complex has been achieved, thus now adding an early d‐block metal to the small group of mid‐ and late‐d‐block metals (Mo, Fe, Ru, Os, Co) that catalytically produce NH(3) by N(2) reduction and protonolysis under homogeneous, abiological conditions. Reduct...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Doyle, Laurence R., Wooles, Ashley J., Jenkins, Lucy C., Tuna, Floriana, McInnes, Eric J. L., Liddle, Stephen T.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6003280/
https://ncbi.nlm.nih.gov/pubmed/29633444
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802576
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