Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine–Titanium Complex

Catalytic reduction of N(2) to NH(3) by a Ti complex has been achieved, thus now adding an early d‐block metal to the small group of mid‐ and late‐d‐block metals (Mo, Fe, Ru, Os, Co) that catalytically produce NH(3) by N(2) reduction and protonolysis under homogeneous, abiological conditions. Reduct...

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Veröffentlicht in:Angew Chem Int Ed Engl
Hauptverfasser: Doyle, Laurence R., Wooles, Ashley J., Jenkins, Lucy C., Tuna, Floriana, McInnes, Eric J. L., Liddle, Stephen T.
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2018
Schlagworte:
Communications
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6003280/
https://ncbi.nlm.nih.gov/pubmed/29633444
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802576
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