Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin

Neutral mesoionic carbenes (MICs) have emerged as an important class of carbene, however they are found in the free form or ligated to only a few d‐block ions. Unprecedented f‐block MIC complexes [M(N′′)(3){CN(Me)C(Me)N(Me)CH}] (M=U, Y, La, Nd; N′′=N(SiMe(3))(2)) are reported. These complexes were p...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Seed, John A., Gregson, Matthew, Tuna, Floriana, Chilton, Nicholas F., Wooles, Ashley J., McInnes, Eric J. L., Liddle, Stephen T.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5601227/
https://ncbi.nlm.nih.gov/pubmed/28719735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706546
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