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Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
Neutral mesoionic carbenes (MICs) have emerged as an important class of carbene, however they are found in the free form or ligated to only a few d‐block ions. Unprecedented f‐block MIC complexes [M(N′′)(3){CN(Me)C(Me)N(Me)CH}] (M=U, Y, La, Nd; N′′=N(SiMe(3))(2)) are reported. These complexes were p...
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| Wydane w: | Angew Chem Int Ed Engl |
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| Główni autorzy: | , , , , , , |
| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
John Wiley and Sons Inc.
2017
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5601227/ https://ncbi.nlm.nih.gov/pubmed/28719735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706546 |
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