Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin

Neutral mesoionic carbenes (MICs) have emerged as an important class of carbene, however they are found in the free form or ligated to only a few d‐block ions. Unprecedented f‐block MIC complexes [M(N′′)(3){CN(Me)C(Me)N(Me)CH}] (M=U, Y, La, Nd; N′′=N(SiMe(3))(2)) are reported. These complexes were p...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Seed, John A., Gregson, Matthew, Tuna, Floriana, Chilton, Nicholas F., Wooles, Ashley J., McInnes, Eric J. L., Liddle, Stephen T.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2017
Teme:
Communications
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5601227/
https://ncbi.nlm.nih.gov/pubmed/28719735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706546
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