Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin

Neutral mesoionic carbenes (MICs) have emerged as an important class of carbene, however they are found in the free form or ligated to only a few d‐block ions. Unprecedented f‐block MIC complexes [M(N′′)(3){CN(Me)C(Me)N(Me)CH}] (M=U, Y, La, Nd; N′′=N(SiMe(3))(2)) are reported. These complexes were p...

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Seed, John A., Gregson, Matthew, Tuna, Floriana, Chilton, Nicholas F., Wooles, Ashley J., McInnes, Eric J. L., Liddle, Stephen T.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2017
Soggetti:
Communications
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5601227/
https://ncbi.nlm.nih.gov/pubmed/28719735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706546
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