Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin

Neutral mesoionic carbenes (MICs) have emerged as an important class of carbene, however they are found in the free form or ligated to only a few d‐block ions. Unprecedented f‐block MIC complexes [M(N′′)(3){CN(Me)C(Me)N(Me)CH}] (M=U, Y, La, Nd; N′′=N(SiMe(3))(2)) are reported. These complexes were p...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Seed, John A., Gregson, Matthew, Tuna, Floriana, Chilton, Nicholas F., Wooles, Ashley J., McInnes, Eric J. L., Liddle, Stephen T.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5601227/
https://ncbi.nlm.nih.gov/pubmed/28719735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706546
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