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Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors
We report herein that copper alkynyl nanoclusters show metal-core dependent properties via a charge-transfer mechanism, which enables new understanding of their structure–property relationship. Initially, nanoclusters 1 and 2 bearing respective Cu(i)(15) (C1) and Cu(i)(28) (C2) cores were prepared a...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7003970/ https://ncbi.nlm.nih.gov/pubmed/32055367 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03455b |
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