Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors

We report herein that copper alkynyl nanoclusters show metal-core dependent properties via a charge-transfer mechanism, which enables new understanding of their structure–property relationship. Initially, nanoclusters 1 and 2 bearing respective Cu(i)(15) (C1) and Cu(i)(28) (C2) cores were prepared a...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Zhang, Leon Li-Min, Zhou, Guodong, Zhou, Guoqing, Lee, Hung-Kay, Zhao, Ni, Prezhdo, Oleg V., Mak, Thomas C. W.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2019
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7003970/
https://ncbi.nlm.nih.gov/pubmed/32055367
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03455b
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