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Electron localization in a mixed-valence diniobium benzene complex
Reaction of the neutral diniobium benzene complex {[Nb(BDI)N( t )Bu](2)(μ-C(6)H(6))} (BDI = N,N′-diisopropylbenzene-β-diketiminate) with Ag[B(C(6)F(5))(4)] results in a single electron oxidation to produce a cationic diniobium arene complex, {[Nb(BDI)N( t )Bu](2)(μ-C(6)H(6))}{B(C(6)F(5))(4)}. Invest...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , , , , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811154/ https://ncbi.nlm.nih.gov/pubmed/29560186 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02705a |
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