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High-resolution X-ray absorption spectroscopy as a probe of crystal-field and covalency effects in actinide compounds

Applying the high-energy resolution fluorescence-detection (HERFD) mode of X-ray absorption spectroscopy (XAS), we were able to probe, for the first time to our knowledge, the crystalline electric field (CEF) splittings of the [Formula: see text] shell directly in the HERFD-XAS spectra of actinides....

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Butorin, Sergei M., Kvashnina, Kristina O., Vegelius, Johan R., Meyer, Daniel, Shuh, David K.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4961124/
https://ncbi.nlm.nih.gov/pubmed/27370799
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1601741113
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