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High-resolution X-ray absorption spectroscopy as a probe of crystal-field and covalency effects in actinide compounds
Applying the high-energy resolution fluorescence-detection (HERFD) mode of X-ray absorption spectroscopy (XAS), we were able to probe, for the first time to our knowledge, the crystalline electric field (CEF) splittings of the [Formula: see text] shell directly in the HERFD-XAS spectra of actinides....
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| Publié dans: | Proc Natl Acad Sci U S A |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
National Academy of Sciences
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4961124/ https://ncbi.nlm.nih.gov/pubmed/27370799 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1601741113 |
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