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How bulky ligands control the chemoselectivity of Pd-catalyzed N-arylation of ammonia

Steric bulk has been recognized as a central design principle for supporting ligands in the widely utilized Buchwald–Hartwig amination. In a recent example, it was shown that a Pd-catalyst carrying a phosphine ligand can successfully aminate aryl halides using ammonia as the nitrogen source. Interes...

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Detaylı Bibliyografya
Yayımlandı:Chem Sci
Asıl Yazarlar: Kim, Seoung-Tae, Kim, Suyeon, Baik, Mu-Hyun
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: The Royal Society of Chemistry 2019
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC8145866/
https://ncbi.nlm.nih.gov/pubmed/34084357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03095f
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